Synthesis and structure of nitrones derived from 2-trifluoromethyl bornane 3-imines
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چکیده
منابع مشابه
Synthesis and characterization of derived imines from 4-imino-5,6,7,8-tetrahydro-1-benzothieno[2,3-d]pyrimidin-3(4H)-amine
The synthesis and characterization of derived imines from 4-imino-5,6,7,8-tetrahydro-1-benzo thieno[2,3-d]pyrimidin-3(4H)-amine 3 has been developed in 3 steps through the reaction of heteroaromatic o-aminonitrile 1 with triethyl orthoformate afforded the corresponding imido ester 2 followed by cyclization with hydrazine hydrate to furnish iminothienopyrimidineamine 3 and finally the imination ...
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An efficient method for highly diastereoselective synthesis of quaternary α-trifluoromethyl α-amino acids was developed via indium mediated allylation of (R)-phenylglycinol methyl ether based imines of trifluoropyruvate in good yields with high diastereoselectivities at room temperature; to illustrate the application of this method in organic synthesis, 2-allyl-2-(trifluoromethyl) aziridine was...
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INTRODUCTION Pinacol coupling was first described by Fittig in 1859, when he reported the formation of 2,3dimethyl-2,3-butanediol (1) from acetone and sodium metal. Since then, this ketyl radical anion coupling process has undergone significant advancement, including the development of asymmetric variants. 3 Alternatives to use of strong reducing metals are low valent transition metals and lant...
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ژورنال
عنوان ژورنال: Journal of Fluorine Chemistry
سال: 2010
ISSN: 0022-1139
DOI: 10.1016/j.jfluchem.2010.01.001